NHD (X 2A")

Version 1
Date of Entry September 2009
Contributor K. Kobayashi
Lines Listed 298
Frequency / GHz 177.8-517.6
Max N 5
Max K 3
log STR0
log STR1
Isotope Corr.
Egy / (cm-1)
μa / D
μb / D
μc / D
A / MHz 602873.269(53)
B / MHz 243150.415(86)
C / MHz 169875.877(79)
"The Microwave Spectrum of the NHD Radical in the Ground electronic state, (X 2A")," K. Kobayashi, H. Ozeki, S. Saito, M. Tonooka and S. Yamamoto, Journal of Chemical Physics, Volume 107, Pages 9289 -9296(1997).
The coupling scheme of angular momenta,
J = N + S, F1 = J + IN, F2 = J + IH and F = F1 + ID
In the low - N transitions, many components other than the main selection rule, ΔF = ΔF2 = ΔF1 = ΔJ, were also observed. These weaker components were often overlapped with the other components.
Unresolved lines were included in the least-squares fit by using the averaged frequency of the component lines weighted by their relative intensities. The weight is usually calculated by first-order theory, that is, intensity of a transition is calculated by using representative basis functions of specific levels.
The relative intensity contain neither dipole moment nor partition function contribution.
When the line is the overlap of the multiple components, the relative intensity shows the summation of those of each components.

Return to Toyama Microwave Atlas.
Kaori Kobayashi (Department of Physics, University of Toyama)
kaori-at-sci.u-toyama.ac.jp (replace -at- with @)
Last update, Sep. 9th 2009